Sodium bicarbonate (or baking soda) has appeared in literature as a pH buffer, which allows for an improvement in performance by having increased pH levels at rest. It’s biggest weakness though, is gastrointestinal distress which can be bypassed by and large by taking the substance 3-4 hours before training or exercise or along with the food. In theory, it has its merits, but it is not advised to be taken for the first time just before an event as it readily increases the chances of GI distress.